PARA-XYLENE MAXIMIZATION-PART VII ALKYLATION OF TOLUENE WITH METHANOL AND DIFFUSION EFFECTS ON DIFFERENTLY HYDROFLUORINATED H-ZSM-5 CATALYSTS

Conversion of Methanol on CuO/H-MOR and CuO/H-ZSM-5 Catalysts.

This paper deals with maximizing dimethyl ether (DME) production from methanol due to its industrial importance as a future diesel fuel. The high acidity and the micro-porous structure of the catalysts encouraged this reaction. Catalysts containg 6% CuO supported on H-ZSM-5 and H-MOR zeolites give high activities for DME production. The 6% CuO/HMOR is more selective for DME production, while th...

Dehydration of Methanol to Dimethyl Ether Employing Modified H-ZSM-5 Catalysts

Investigation of Methanol Reaction Chemistry on H-ZSM-5 and -11

In order to gain a better understanding of the chemistry of methanl-to-hydro-carbon conversion, it is necessary to determine the nature of the primary reaction products. Experiments carried out in this work on H-ZSM-11, using a continuous flow reactor linked to an on-line gas chromatograph demonstrated that ethylene and methane are the primary reaction products. The results obtained using s...

Methanol - to - hydrocarbons conversion over MoO 3 / H - ZSM - 5

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Structure of toluene6.4-ZSM-5 and the toluene disproportionation reaction on ZSM-5.

The structure of a high-loading complex of ZSM-5 with 6.4 toluene molecules per unit cell has been determined by single-crystal X-ray diffraction. At least three kinds of toluene molecules were identified in the unit cell. Two disordered toluene molecules were located at the intersection of the straight and sinusoidal channels, the third in the sinusoidal channel. One (TOL1) of the two toluene ...